Rare earth elements in Huronian (Lower Proterozoic) sedimentary rocks: Composition and evolution of the post-Kenoran upper crust     

Scott M McLennan  B.J Fryer  Grant M Young 《Geochimica et cosmochimica acta》1979,43(3):375-388

The Huronian sequence (Lower Proterozoicl. north of Lake Huron, contains tillites and abundant fine-grained sedimentary rocks. Analyses of rare earth elements (REE) in the matrix of tillite samples from the Gowganda Formation (~ 2.3 Gal is considered to be a reasonable estimate of upper crustal REE abundances for the region north of Lake Huron at the time of Gowganda deposition. The average is characterized by a moderately steep pattern (σLREEσHREE = 9.1) and a slight negative europium anomaly ($\text{Eu}\text{Eu1}\text{= 0.89}$). This pattern is similar to estimates of the composition of the surface of the Canadian Shield and is intermediate between estimates of typical Archean and post-Archean sedimentary rocks. REE patterns for framework granitoid clasts from the tillite suggest that K-rich granites, which were apparently unimportant in the formation of Archean sedimentary rocks, were abundant in the source regions of the Gowganda Formation. This may explain the intermediate nature of the Gowganda pattern.Comparison of the tillites and associated Gowganda mudstones suggests that previous estimates of upper crustal REE abundances, which were based on the analyses of fine-grained sedimentary rocks, may be systematically high. Relative distributions, however, are the same.Analyses of mudstones from the McKim. Pecors. Serpent Gowganda Lorrain and Gordon Lake Formations suggest rapid evolution in the composition of the exposed upper crust at the close of the Kenoran orogeny. REE patterns at the base of the Huronian are similar to typical Archean sedimentary rocks. REE characteristics change up section: patterns at the top resemble typical post-Archean sedimentary rocks.It is inferred that an essentially episodic change from an early exposed upper crust dominated by a tonalite-greenstone suite to one approximating granodioritic composition is recorded in Huronian sedimentary rocks. A deviation from the evolutionary trend of the Huronian, documented in the Gowganda Formation, may be related to the glacial origin of the Gowganda.  相似文献   

Variations in Cr content of magnetite from the upper zone of the Bushveld Complex — evidence for heterogeneity and convection currents in magma chambers     

R. Grant Cawthorn  T.S. McCarthy 《Earth and Planetary Science Letters》1980,46(3):335-343

Mineral separates of pure magnetite from the upper zone of the Bushveld Complex have been analysed for Cr. Detailed sampling within layers of massive magnetite indicates that the Cr content frequently shows an extremely rapid but regular depletion with height (for example, by a factor of seven over 85 cm of massive magnetite), with sudden reversals of variable magnitude. Rayleigh Law fractionation, from a homogeneous liquid of the volume now seen as cumulate rocks overlying the sampled horizons, cannot satisfy these observed concentration gradients. A diffusion-controlled crystallization model is preferred. In another vertical section of massive magnetite the Cr content remains constant with increasing height, and is interpreted as indicating a steady state situation where the rate of depletion of Cr by magnetite fractionation is balanced by the rate of diffusive addition into the crystallization zone. Reversals in Cr content sometimes occur in the middle of pure magnetite layers and are attributed to convective overturn in the magma chamber. These results provide geochemical support for the model of convection cells and bottom crystallization in large magma reservoirs as proposed by Jackson [20]. Depletion of compatible elements in this bottom layer causes chemical inhomogeneity in the magma.Sections, composed of several layers of magnetite sandwiched between magnetite-bearing gabbro, have also been studied. In one case, a steady decrease in Cr content with increasing height in the separated magnetite was observed; in another, several irregular reversals were found. There appears to be no systematic relation between convection cycles, the depletion in Cr and the formation of pure magnetite layers, indicating that the chemical composition of the magma does not control the production of monomineralic layers. The fluctuating pressure model envisaged by Cameron [16] for the formation of such layers is entirely consistent with these data.  相似文献   

Determination of predevelopment denudation rates of an agricultural watershed (Cayaguás River, Puerto Rico) using in-situ-produced Be in river-borne quartz     

Erik Thorson Brown  Robert F. Stallard  Matthew C. Larsen  Didier L. Bourls  Grant M. Raisbeck  Franoise Yiou 《Earth and Planetary Science Letters》1998,160(3-4):723-728

Accurate estimates of watershed denudation absent anthropogenic effects are required to develop strategies for mitigating accelerated physical erosion resulting from human activities, to model global geochemical cycles, and to examine interactions among climate, weathering, and uplift. We present a simple approach to estimate predevelopment denudation rates using in-situ-produced cosmogenic ¹⁰Be in fluvial sediments. Denudation processes in an agricultural watershed (Cayaguás River Basin, Puerto Rico) and a matched undisturbed watershed (Icacos River Basin) were compared using ¹⁰Be concentrations in quartz for various size fractions of bed material. The coarse fractions in both watersheds bear the imprint of long subsurface residence times. Fine material from old shallow soils contributes little, however, to the present-day sediment output of the Cayaguás. This confirms the recent and presumably anthropogenic origin of the modern high denudation rate in the Cayaguás Basin and suggests that pre-agricultural erosional conditions were comparable to those of the present-day Icacos.  相似文献   

The variation of temperature with time and hydrocarbon maturation in sedimentary basins formed by extension     

Dan McKenzie 《Earth and Planetary Science Letters》1981,55(1):87-98

When a sedimentary basin is formed by extension both the subsidence history and the temperature gradient can be calculated. Hence the time-temperature history of any stratum can be obtained. Three types of behaviour occur. The temperature of material which never reaches depths greater than about 4 km increases at all times. The time-temperature history of material which finally sinks to greater depths reaches a maximum during the subsidence history. The time at which this maximum occurs decreases as the depth increases. At greater depths the maximum temperature occurs at the time the basin is formed. The time-temperature history is then used to calculate Lopatin's maturation index for each stratum as a function of time, and the index plotted as a function of depth and time for different amounts of extension. The maximum temperature at a given depth, and hence Lopatin's index, is almost independent of the amount of extension when the age of the basin is greater than about 150 Ma. Similar calculations taking account of sediment compaction show the same behaviour, though the maturity of the material at a given depth is increased. Because both Lopatin's index and its calibration are empirical it is important to develop new maturation indices based on individual molecular reactions whose activation energies can be determined in the laboratory.  相似文献   

Magmatic andalusite from the South Mountain batholith,Nova Scotia   总被引：3，自引：0，他引：3  

D. B. Clarke  C. B. McKenzie  G. K. Muecke  S. W. Richardson 《Contributions to Mineralogy and Petrology》1976,56(3):279-287

Accessory andalusite has been found in some late-stage granitic differentiates of the South Mountain batholith. The andalusite is petrographically distinct from the andalusite of the thermal aureole, and it occurs in regions of the batholith which show little evidence of contamination by the country rocks. Analyses of biotites from andalusite-bearing and andalusite-free phases suggest that those coexisting with andalusite actually grew in equilibrium with the andalusite. It is concluded that magmatic andalusite must be confined mainly to water-saturated, peraluminous, epizonal granites, and some possible P-T paths for the crystallization of magmatic andalusite are considered.  相似文献   

The isotopic composition of strontium and oxygen in lavas from St. Helena,South Atlantic     

Norman K. Grant  James L. Powell  Flora R. Burkholder  John V. Walther  Max L. Coleman 《Earth and Planetary Science Letters》1976,31(2):209-223

Strontium and oxygen isotope measurements on the alkali basalt-trachyte-phonolite suite of St. Helena show that some of the late-fractionated rocks are enriched in ⁸⁷Sr and depleted in ¹⁸O relative to the older basalts. The data rule out both the formation of the late-fractionated rocks by the partial melting of hydrothermally altered oceanic crust and the contamination of the volcanic rocks by oceanic sediment. It also appears to be incompatible with models based either on the melting of previously fractionated and crystallized liquids in the volcanic pile, or the long-term fractionation of lavas over several millions of years in a sub-volcanic magma chamber.It is concluded that hydrothermal interaction with meteoric water is the most important cause of the ¹⁸O depletion. If the interaction occurred at widely differing temperatures, and involved meteoric and seawaters, it might conceivably have caused both the oxygen and strontium isotope heterogeneities.  相似文献   

The orientation of the stress axes within sinking slabs     

Dan McKenzie 《Earth and Planetary Science Letters》1976,31(2):305-307

In principle it should be possible to obtain information about the orientation of the stress axes within a sinking slab from the first motions observed at a single suitably placed seismic station. This idea is tested on the Tonga-Fiji-Kermadec Arc, using the short-period vertical seismograms from Port Moresby, and the orientations so obtained agree with those derived from fault plane solutions.  相似文献   

Photogrammetric survey of the structural geology of the Sudbury-McGregor Bay District,Ontario, Canada: a discussion     

Grant M. Young 《International Journal of Earth Sciences》1974,63(2):786-788

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The geothermal potential of the basal clastics of Saskatchewan,Canada   总被引：1，自引：0，他引：1  

Grant Ferguson  Stephen E. Grasby 《Hydrogeology Journal》2014,22(1):143-150

The Winnipeg and Deadwood formations form deep clastic reservoirs in Saskatchewan, Canada, with temperatures exceeding 40 °C over most of southern Saskatchewan and reaching 100 °C in southwestern Saskatchewan. At these temperatures, the formations have geothermal potential for development of direct use and electricity generation systems. Numerous disposal wells operating at rates of 30 L/s or more are currently installed in these formations, suggesting that electricity could be generated at rates exceeding 2 megawatts of electrical output (MW_e) from individual wells. These basal clastic units, thus, could provide significant energy supply over a broad region of Saskatchewan.  相似文献   

The NASA Astrophysics Data System: Free Access to the Astronomical Literature On-line and through Email     

Guenther Eichhorn  Alberto Accomazzi  Carolyn S. Grant  Michael J. Kurtz  Stephen S. Murray 《Astrophysics and Space Science》2002,282(1):299-340

The Astrophysics Data System (ADS) provides access to the astronomical literature through the World Wide Web. It is a NASA funded project and access to all the ADS services is free to everybody world-wide. The ADS Abstract Service allows the searching of four databases with abstracts in Astronomy, Instrumentation, Physics/Geophysics, and the LANL Preprints with a total of over 2.2 million references. The system also provides access to reference and citation information, links to on-line data, electronic journal articles, and other on-line information. The ADS Article Service contains the full articles for most of the astronomical literature back to volume 1. It contains the scanned pages of all the major journals (Astrophysical Journal, Astronomical Journal, Astronomy & Astrophysics, Monthly Notices of the Royal Astronomical Society, and Solar Physics), as well as most smaller journals back to volume 1.The ADS can be accessed through any web browser without signup or login. Alternatively an email interface is available that allows our users to execute queries via email and to retrieve scanned articles via email. This might be interesting for users on slow or unreliable links, since the email system will retry sending information automatically until the transfer is complete. There are now 9 mirror sites of the ADS available in different parts of the world to improve access. The ADS is available at: http://ads.harvard.edu This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献